I bought my dad some stuff called Satan's Blood (I think) from a hot sauce shop awhile back. I forget the scoville units, but at the time (6-7 years ago) I was told it's the hottest stuff available. Supposedly if you stuck a toothpick in it, and then dipped that toothpick in a pot of chili, it would ruin the the whole pot. Had to sign a waiver for it and everything. It's really more of a novelty than anything else though, as I can't imagine anyone actually using it (my dad certaintly hasn't).
Edit: After a quick google search I came across a pretty cool site:
http://www.chez-williams.com/Hot%20Sauce/hothome.htm
Apparently the hot sauce I was referring to is 800,000 scoville unitsAnd amazingly it's about half way down the list.
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And amazingly it's about half way down the list.

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